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BBO

Beta-Barium Borate (β-BaB2O4,BBO) 

 

*Second, third, fourth and fifth harmonic generation

*Frequency double, tripling and mixing of Dye and Ti :Sapphire lasers

*Optical Parametric amplifiers(OPA) and optical parametric oscillators(OPO)

 

Advantages:

*Broad phase-matching wavelength range from 409.6 nm to 3500 nm
*Wide transmission region from 190 nm to 3500 nm
*Large effective SHG coefficient about 6 times greater than that of KDP crystal
*High damage threshold of 10 GW/cm2 for 100 ps pulse-width at 1064 nm
*High optical homogeneity with Δn ~ 10-6/cm
*Wide temperature-bandwidth of about 55°C(for type I SHG 1064nm)
*Good Mechanical and physical properties

 

Crystal Structure:

Trigonal, space group R3c

Lattics Parameters:

a=b=12.532Å, c=12.717Å, Z=6

Melting point

About 1095

Mohs Hardness

4

Density

3.85g/cm3

Thermal Conductivity

1.2W/m/K(c): 1.6W/m/K(//c)

Thermal Expansion Coefficients

  a11=4x10-6/K; a33=36x10-6/K

Transparency Range:

190-3500nm

SHG Phase Matchable Range

409.6-3500nm(Type I)    525-3500nm(Type II)

Therm-optic Coefficients(/)

dno/dT=-16.6X10-6

dne/dT=-9.3X10-6

Absorption Coefficients

<0.1%/cm at 1064nm         <1%/cm at 532nm

Angle Acceptance

0.8mrad-cm      (θ, Type I,1064 SHG)   

1.27mrad-cm    (θ, Type II,1064 SHG)

Temperature Acceptance

55-cm

Spectral Acceptance

1.1nm-cm

Walk-off Angle

2.7°   (Type I 1064 SHG)

3.2°  (Type II 1064 SHG)

NLO Coefficients

deff (I)=d31sinθ+(d11cosΦ-d22sin3Φ)cosθ

deff (II)=(d11sin3Φ+d22cos3Φ)cos2θ

Non-vanished NLO susceptibilities

d11=5.8xd36(KDP)

d31=0.05xd11

d22<0.05xd11

Sellmeier Equations(λ in μm )

no2=2.7359+0.01878 / (λ2-0.01822) -0.01354 λ2

ne2=2.3753+0.01224 / (λ2-0.01667) -0.01516 λ2

Electro-optic coefficients:

r22=2.7pm/V

Half-wave voltage:

7KV (at 1064nm,3*3*20mm3)

Resistivity:

>1011 ohm-cm

Relative Dielectric Constant:

εs11o:6.7

εs33o:8.1

Tan δ<0.001

 

  Specifications 

Dimension tolerance:

±0.1mm

Flatness:

l/8 @633nm

Surface quality: Scratch/Dig

10/5

Parallelism:

better than 20 arc sec.

Perpendicularity:

better than 15 arc min

Angle tolerance:

< +/-0.5°

AR coating:

P-coating, AR or BBAR coatings

Residual reflectivity:

R1064<0.2% ,R532<0.5%,R355<0.5%,R266<0.5%

Clear aperture:

>90% central area

Transmitting wavefront distortion:

less than l/8 @ 633nm

 

  Standard products

Part No

Sizes

Application

Coating

  BOH4407  

4*4*7mm

S/T/FHG@1064nm, 

AR/AR

 BOS8407

8*4*7mm

SHG for Dye laser

P-Coating

 BOS5501

5*5*1mm

SHG@800nm

P-Coating

 BOS5500

5*5*0.5mm

SHG@800nm

p-Coating

 BOO4415

4*4*12mm

OPO

AR/AR

 

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