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LiNbO3

NLO / EO Crystals --------- LiNbO3

LiNbO3 Crystal is widely used as frequency doublers for wavelength > 1 mm and optical

parametric oscillators (OPOs) pumped at 1064 nm as well as quasi-phase-matched (QPM)

devices. Due to its large Electro-Optic (E-O) and Acousto-Optic (A-O) coefficients

 

Also,LiNbO3 is widely used as electro-optic modulator and Q-switch for Nd:YAG, Nd:YLF

and Ti:Sapphire lasers as well as modulator for fiber optics, etc. The transverse modulation

is mostly employed for LiNbO3 crystal.

 

If the light propagates in z-axis and electric field applies to x-axis, the refractive retardation

will be G = p Lnr22V/ l d. The electro-optic coefficients of LiNbO3; are:
r 33 = 32 pm/V, r 31 = 10 pm/V, r 22 = 6.8 pm/V at low frequency
r 33 = 31 pm/V, r 31 = 8.6 pm/V, r 22 = 3.4 pm/V at high electric frequency.

 

MgO: LiNbO3 and ZnO: LiNbO3 crystals have similar electro-optic properties to LiNbO3 but

with higher damage threshold.

 

The refractive index of an optical medium is altered by the presence of sound, this is

called acousto-optic effect which can be used in many devices include optical modulators,

switches, deflectors, filters, frequency shifters and spectrum analyzers.

 

DeLn Optics provides high quality and large size LiNbO3 crystals for laser frequency

doublers, OPOs and quasi-phase-matched doublers, as well as waveguide substrate and SAW

wafers. High quality LiNbO3 finished components with aperture of (2 - 15) x (2 - 15) mm2

and length up to 50 mm for frequency doublers and optical parametric oscillators (OPOs),

50x50x1 mm3 or Dia. 3" x 1 mm LiNbO3 substrate for waveguide optics, and Dia. 3" SAW wafers

are available with high volume and at low price.

Crystal Structure Trigonal, space group R 3c
Cell Parameters a = 0.515, c = 13.863, Z = 6
Melting Point 1255 +/-5
Curie Point 1140 +/-5
Mohs Hardness 5
Density 4.64 g/cm 3
Absorption Coefficient ~ 0.1%/cm @ 1064 nm
Solubility: insoluble in H 2 O
Relative Dielectric Constant e T11/e 0 : 85
e T33/e 0 : 29.5
Thermal Expansion Coefficients ||a, 2.0 x 10 -6 /K @ 25
||c, 2.2 x 10 -6 /K @ 25
Thermal Conductivity 38 W /m /K @ 25
Transparency Range 420 - 5200 nm
Refractive Indices n e = 2.146, n o = 2.220 @ 1300 nm
n e = 2.156, n o = 2.322 @ 1064 nm
n e = 2.203, n o = 2.286 @ 632.8 m
Optical Homogeneity ~ 5 x 10 -5 /cm
Sellmeier Equations( l in m m) n o 2 ( l ) = 4.9048+0.11768/(l2- 0.04750) - 0.027169l2
n e 2 ( l) = 4.5820+0.099169/( l2 - 0.04443) - 0.021950 l2

 

NLO Coefficients d 33 = 34.4 pm/V
d 31 = d 15 = 5.95 pm/V
d 22 = 3.07 pm/V
Electro-Optic Coefficients g T 33 = 32 pm/V, g S 33 = 31 pm/V
g T 31 = 10 pm/V, g S 31 = 8.6 pm/V
g T 22 = 6.8 pm/V, g S 22 = 3.4 pm/V,
Damage Threshold 200 MW/cm 2 (10 ns)
Efficiency NLO Coefficients d eff =5.7pm/V or~14.6xd 36 (KDP) for frequency doubling 1300 nm;
d eff =5.3pm/V or~13.6xd 36 (KDP) for OPO pumped at 1300nm;
d eff =17.6pm/V or~45xd 36(KDP)for quasi-phase-matched structure

 

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